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RE: Europa-List: Expanding brake fluid?

Subject: RE: Europa-List: Expanding brake fluid?
From: Rob Housman <RobH@hyperionef.com>
Date: Mon, 12 Jan 2004 11:58:46

As you probably can guess, my choice was silicone brake fluid, for its clear
advantages.  Most of your points are strictly academic, and apply more to
automotive rather than aviation systems:


LONG/SPONGY PEDAL - the compressibility of the silicone-based fluid is up to
three times that of the more common glycol-based types, so needs more pedal
travel to actuate. Its viscosity is twice that of the glycol-based fluid -
meaning it is thicker. This equates to slow fill rates that can trap air,
and results in bleeding difficulties.

Within the temperature and pressure limits encountered in automotive or
aviation brake systems any hydraulic fluid is essentially incompressible.
The higher viscosity may increase the fill time, but even in the Tri-Gear
where you have your head in the footwell and the your nose practically up
against the go cart master cylinders in order to see what you are doing, the
time is not unreasonable.  Bleeding was likewise a relatively quick process.


SUDDEN LOSS OF BRAKES - Entrapped air suffers gasification at relatively low
temperatures, causing a vapour-lock effect. It's immiscibility causes any
free water caught in the system to boil at relatively low temperatures -
producing a vapour-lock. Glycol-based fluids absorb water (the water
dissolves into the fluid), and although this will reduce the boiling point,
it is unlikely to cause severe vapour-lock at low temperatures.

The hydraulic system is completely sealed in the Europa Tri-Gear (and I
presume the same scheme is used in the Monowheel, except with only one
master cylinder and slave cylinder), ergo, there is no possibility of water
entering the system except while filling with brake fluid.  In an automotive
system with a fluid reservoir water can enter through the vent in the
reservoir cap.


HANGING ON - In disc brake systems, the sole mechanism for returning the
pads to their normal 'not in use' position away from the disc is the
tendency of the seals to recover to their 'at rest' attitude once the pedal
is released. The low lubricity of the silicone-based fluid works against
this recovery; it's high viscosity amplifying this effect

While this is technically correct as far as it goes, the sole mechanism
argument fails because it is not the sole mechanism.  Braking generates
heat, causing the mechanical components expand, and once these components
return to ambient temperature the pads and disc are no longer in contact.


Fluid Compatibility
Brake system materials must be compatible with the system fluid.
<snip>

Silicone brake fluid is compatible with all seal materials, making it
unnecessary to replace the seals in some of the Europa supplied components
(again assuming similarities between the Monowheel and Tri-Gear).


Water absorption and corrosion
<snip>

Everything you said about the advantages and disadvantages of each fluid is
correct, especially for automotive braking systems, but moot for the Europa.
With no water in a sealed system there will be no corrosion.


Fluid boiling point
<snip>

Again, literally correct, but moot, primarily because the Europa system is
sealed, but also because it would be impossible to generate enough heat in
the Europa's short braking distance to make any difference whatsoever - the
lowest grade brake fluid will never get anywhere near its boiling point.
Although most of us don't fly high enough for it to make a difference, it
does get cold at altitudes approaching the flight levels.  Today, for
example, the temperature at 12,000 MSL over the western US is in the range
of -3 to -9 C, and at 18,000 MSL the range is -18 to -22 C.


Brake system contamination
<snip>

Here's a point that I can agree with wholeheartedly.  Once we select a fluid
type we must stick with it, and I assume that we are not going to "top off"
the system with an incompatible fluid.


The only real disadvantage of silicone brake fluid for the Europa is that if
it is spilled on something that will be painted, the paint won't stick.


Best regards,

Rob Housman
Europa XS Tri-Gear A070
Airframe complete
Irvine, CA

-----Original Message-----
From: owner-europa-list-server@matronics.com
[mailto:owner-europa-list-server@matronics.com]On Behalf Of ivor.phillips
Subject: Re: Europa-List: Expanding brake fluid?

<ivor.phillips@ntlworld.com>

LONG/SPONGY PEDAL - the compressibility of the silicone-based fluid is up to
three times that of the more common glycol-based types, so needs more pedal
travel to actuate. Its viscosity is twice that of the glycol-based fluid -
meaning it is thicker. This equates to slow fill rates that can trap air,
and results in bleeding difficulties.

SUDDEN LOSS OF BRAKES - Entrapped air suffers gasification at relatively low
temperatures, causing a vapour-lock effect. It's immiscibility causes any
free water caught in the system to boil at relatively low temperatures -
producing a vapour-lock. Glycol-based fluids absorb water (the water
dissolves into the fluid), and although this will reduce the boiling point,
it is unlikely to cause severe vapour-lock at low temperatures.

HANGING ON - In disc brake systems, the sole mechanism for returning the
pads to their normal 'not in use' position away from the disc is the
tendency of the seals to recover to their 'at rest' attitude once the pedal
is released. The low lubricity of the silicone-based fluid works against
this recovery; it's high viscosity amplifying this effect

> DOT 3/4/5.1 Verses DOT 5. Which brake fluid should I use?
        1.. Fluid compatibility with the brake system rubber, plastic and
metal components.
        2.. Water absorption and corrosion.
        3.. Fluid boiling point and other physical characteristics.
        4.. Brake system contamination and sludging.
      First of all, it's important to understand the chemical nature of
brake fluid. DOT 3 brake fluids are mixtures of glycols and glycol ethers.
DOT 4 contains borate esters in addition to what is contained in DOT 3.
These brake fluids are somewhat similar to automotive anti-freeze (ethylene
glycol) ,. DOT 5 is silicone chemistry.

      Fluid Compatibility
      Brake system materials must be compatible with the system fluid.
Compatibility is determined by chemistry, and no amount of advertising,
wishful thinking or rationalizing can change the science of chemical
compatibility. Both DOT 3-4 and DOT 5 fluids are compatible with most brake
system materials except in the case some silicone rubber external components
such as caliper piston boots, which are attacked by silicon fluids and
greases.

      Water absorption and corrosion
      The big bugaboo with DOT 3-4 fluids always cited by silicone fluid
advocates is water absorption. DOT 3-4 glycol based fluids, just like
ethylene glycol antifreezes, are readily miscible with water. Long term
brake system water content tends to reach a maximum of about 3%, which is
readily handled by the corrosion inhibitors in the brake fluid formulation.
Since the inhibitors are gradually depleted as they do their job, glycol
brake fluid, just like anti-freeze, needs to be changed periodically. Follow
BMW's recommendations. DOT 5 fluids, not being water miscible, must rely on
the silicone (with some corrosion inhibitors) as a barrier film to control
corrosion. Water is not absorbed by silicone as in the case of DOT 3-4
fluids, and will remain as a separate globule sinking to the lowest point in
the brake system, since it is more dense.

      Fluid boiling point
      DOT 5.1 glycol based fluid has a higher boiling point (520F) than DOT
4 (446F), DOT3(401F) and all fluids will exhibit a reduced boiling point as
water content increases. DOT 5 in its pure state offers a higher boiling
point (500F) however if water got into the system, and a big globule found
its way into a caliper, the water would start to boil at 212F causing a
vapor lock condition [possible brake failure -ed.]. By contrast, DOT 3 fluid
with 3% water content would still exhibit a boiling point of 300F. Silicone
fluids also exhibit a 3 times greater propensity to dissolve air and other
gasses which can lead to a "spongy pedal" and reduced braking at high
altitudes.

      DOT 3/4/5.1 fluids are mutually compatible, the major disadvantage of
such a mix being a lowered boiling point. In an emergency, it'll do.
Silicone fluid will not mix, but will float on top. From a lubricity
standpoint, neither fluids are outstanding, though silicones will exhibit a
more stable viscosity index in extreme temperatures, which is why the US
Army likes silicone fluids. Since few of us ride at temperatures very much
below freezing, let alone at 40 below zero, silicone's low temperature
advantage won't be apparent. Neither fluids will reduce stopping distances.

      With the advent of ABS systems, the limitations of existing brake
fluids have been recognized and the brake fluid manufacturers have been
working on formulations with enhanced properties. However, the chosen
direction has not been silicone. The only major user of silicone is the US
Army. It has recently asked the SAE about a procedure for converting from
silicon back to DOT 3-4. If they ever decide to switch, silicone brake fluid
will go the way of leaded gas.

      Brake system contamination
      The single most common brake system failure caused by a contaminant is
swelling of the rubber components (piston seals etc.) due to the
introduction of petroleum based products (motor oil, power steering fluid,
mineral oil etc.) A small amount is enough to do major damage. Flushing with
mineral spirits is enough to cause a complete system failure in a short
time. I suspect this is what has happened when some BMW owners changed to
DOT 5 (and then assumed that silicone caused the problem). Flushing with
alcohol also causes problems. BMW brake systems should be flushed only with
DOT 3 /4/5.1

      If silicone is introduced into an older brake system, the silicone
will latch unto the sludge generated by gradual component deterioration and
create a gelatin like goop which will attract more crud and eventually plug
up metering orifices or cause pistons to stick. If you have already changed
to DOT 5, don't compound your initial mistake and change back. Silicone is
very tenacious stuff and you will never get it all out of your system. Just
change the fluid regularly. For those who race using silicone fluid, I
recommend that you crack the bleed screws before each racing session to
insure that there is no water in the calipers.

      New developments
      Since DOT 4 fluids were developed, it was recognized that borate ester
based fluids offered the potential for boiling points beyond the 446F
requirement, thus came the Super DOT 4 fluids - some covered by the DOT 5.1
designation - which exhibit a minimum dry boiling point of 520F (better than
silicone, but different chemistry).

      Additionally, a new fluid type based on silicon ester chemistry (not
the same as silicon) has been developed that exhibits a minimum dry boiling
point of 590F. It is miscible with DOT 3-4 fluids but has yet to see
commercial usage.


regards
Ivor Phillips

> What's not to like about silicone brake fluid?  The stuff is compatible
with
> all seal materials, does not absorb atmospheric moisture, does not
dissolve
> paint, is rated for higher temperature operation, barely supports
> combustion, does not need to be replaced, and is otherwise virtually
inert.
> Except for price silicone brake fluid seems to be superior to all the
other
> choices in every respect.
>
>




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